Manufacturing of Cuprammonium Rayon

produced by a solution of cellulosic material in cuprammonium hydroxide solution at low temperature in a nitrogen atmosphere, followed by extruding through a spinnerette into a sulphuric acid solution necessary to decompose cuprammonium complex to cellulose. This is a more expensive process than that of viscose rayon. Its fiber cross section is almost round.

Properties Of Rayon

Variations during spinning of viscose or during drawing of filaments provide a wide variety of fibers with a wide variety of properties. These include:
  • Fibers with thickness of 1.7 to 5.0dtex, particularly those between 1.7 and 3.3 dtex, dominate large scale production.
  • Tenacity ranges between 2.0 to 2.6 g/den when dry and 1.0 to 1.5 g/den when wet.
  • Wet strength of the fiber is of importance during its manufacturing and also in subsequent usage. Modifications in the production process have led to the problem of low wet strength being overcome.
  • Dry and wet tenacies extend over a range depending on the degree of polymerization and crystallinity. The higher the crystallinity and orientation of rayon, the lower is the drop in tenacity upon wetting.
  • Percentage elongation-at-break seems to vary from 10 to 30 % dry and 15 to 40 % wet. Elongation-at-break is seen to decrease with an increase in the degree of crystallinity and orientation of rayon.
Rayon Fiber Characteristics

  • Highly absorbent
  • Soft and comfortable
  • Easy to dye
  • Drapes well
The drawing process applied in spinning may be adjusted to produce rayon fibers of extra strength and reduced elongation. Such fibers are designated as high tenacity rayons, which have about twice the strength and two-third of the stretch of regular rayon. An intermediate grade, known as medium tenacity rayon, is also made. Its strength and stretch characteristics fall midway between those of high tenacity and regular rayon.